PROCTOR & GAMBLE -- CASCADE LIQUIGEL, TP MATERIAL SAFETY DATA SHEET NSN: 793000N084875 Manufacturer's CAGE: 60362 Part No. Indicator: A Part Number/Trade Name: CASCADE LIQUIGEL, TP =========================================================================== General Information =========================================================================== Company's Name: PROCTOR & GAMBLE Company's Street: 11530 REED HARTMAN HIGHWAY Company's City: CINCINNATI Company's State: OH Company's Country: US Company's Zip Code: 45241-2422 Company's Emerg Ph #: 800-526-8623 Company's Info Ph #: 800-526-8623 Safety Data Action Code: A Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 01FEB90 Safety Data Review Date: 09APR98 MSDS Serial Number: CGVCP =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: PHOSPHORIC ACID, SODIUM SALT; (WATER SOFTENER-COMPLEX SODIUM PHOSPHATES) AND ING 2 (CERCLA) Ingredient Sequence Number: 01 Ingredient Action Code: A NIOSH (RTECS) Number: TC7000000 CAS Number: 7632-05-5 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: SODIUM CARBONATE; (WATER SOFTENER) Ingredient Sequence Number: 02 Ingredient Action Code: A NIOSH (RTECS) Number: 1004436SC OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: CHLORINE BLEACH; (CLEANING AGENT) Ingredient Sequence Number: 03 Ingredient Action Code: A NIOSH (RTECS) Number: 1011221CB OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: WATER SPOT PREVENTION AGENT Ingredient Sequence Number: 04 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: SILICIC ACID (H2SIO3), DISODIUM SALT; (DISHWASHER & CHINA PROTECTION AGENT) Ingredient Sequence Number: 05 Ingredient Action Code: A NIOSH (RTECS) Number: VV9275000 CAS Number: 6834-92-0 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: THICKENING AGENT Ingredient Sequence Number: 06 Ingredient Action Code: A NIOSH (RTECS) Number: 1001072TA OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: SUDS CONTROL AGENT Ingredient Sequence Number: 07 Ingredient Action Code: A NIOSH (RTECS) Number: 1005257SC OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: COLORANT AND VARIOUS DYES; (COLORANT) Ingredient Sequence Number: 08 Ingredient Action Code: A NIOSH (RTECS) Number: 1011188CD OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: PERFUME Ingredient Sequence Number: 09 Ingredient Action Code: A NIOSH (RTECS) Number: 1000511PU OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: LIGHT GREEN COLOR. THICK/VISCOUS GEL. PRODUCT IS PERFUMED. Boiling Point: N/A Vapor Pressure (MM Hg/70 F): N/A Vapor Density (Air=1): N/A Specific Gravity: 1.4 (H*2O=1) Evaporation Rate And Ref: NOT APPLICABLE Solubility In Water: MISCIBLE Percent Volatiles By Volume: <1 pH: SUPDAT =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: NOT APPLICABLE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Special Fire Fighting Proc: NONE. USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: NONE. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): NONE KNOWN. MAY LOSE AVAILABLE CHLORINE WITH TIME. Materials To Avoid: STRONG ACIDS, AMMONIA/AMMONIA CNTNG PRODS INCL DISHWASHING LIQS AS HAZ FUMES MAY RSLT (PROD CNTNS CHLORING BLEACH). Hazardous Decomp Products: CHLORINE. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE: INGEST: MAY CAUSE VOMITING & MODERATE TO SEVERE ORAL AND/OR GASTROINTESTINAL IRRITATION. SKIN/EYE CONT: MAY CAUSE MODERATE, TRANSIENT IRRITATION. SIGNS & SYMPS OF EXPOS: INGEST: POSSIBLE BURNING SENSATION & IRRITATION OF MOUTH AND THROAT & POSSIBLE NAUSEA, VOMITING AND/OR DIARRHEA. EYE CONT: (EFTS OF OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: HLTH HAZS: MAY CAUSE STINGING, TEARING, ITCHING, SWELLING AND/OR REDNESS. INHAL: MAY CAUSE COUGHING, SORE THROAT, WHEEZING/TRANSITORY SHORTNESS OF BREATH. SKIN: CONTACT W/CONCENTRATED MATERIAL MAY BE DRYING/TRANSIENTLY IRRITATING. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: INGEST: GIVE LG GLASSFUL OF WATER/MILK, DO NOT INDUCE VOMIT. QTIES WHICH MIGHT NORM BE INGESTED IN WORK ENVIRONMENT SHOULD NOT BE OF MAJOR CONCERN. HOWEVER, IF VOL OF INGEST IS > APPROX 1 TSP (ADULT), HOSPITAL EMER ROOM/FAMILY PHYS SHOULD BE CONSULTED. IF PERSISTENT VOMIT OCCURS/IF BLOOD TINGED VOMIT IS PRESENT, MED ATTN SHOULD BE SOUGHT IMMED. EYE: FLUSH THORO W/WATER FOR AT LST 15 MINS. (SUPDAT) =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: FLUSH SMALL (HOUSEHOLD) QUANTITIES DOWN ACCEPTABLE SEWER. PREVENT LARGE SPILLS FROM REACHING WATERWAY. SORBENTS MAY BE USED. FOR LARGE SPILLS, PROTECTIVE CLOTHING (COVERALLS, GLOVES, ETC) MAY BE WORN. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. DO NOT LANDFILL. INCINERATION IS PREFERRED. SMALL OR HOUSEHOLD QUANTITIES MAY BE DISPOSED OF IN SEWER. Precautions-Handling/Storing: NO UNUSUAL PRECAUTIONS NECESSARY. Other Precautions: NONE. =========================================================================== Control Measures =========================================================================== Respiratory Protection: NONE REQUIRED WITH NORMAL USE. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: LOCAL EXHAUST: NONE REQUIRED. MECHANICAL (GENERAL): GENERAL DILUTION VENTILATION IS ACCEPTABLE. OTHER: NONE. Protective Gloves: RUBBER/NEOPRENE FOR DIRECT CONTACT. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). NONE REQUIRED WITH NORMAL USE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: PH: 1% SOLUTION = 10.8, AS IS = 12.2. FIRST AID: SKIN: IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY WITH WATER. IF SYMPTOMS PERSIST OR REOCCUR, DISCONTINUE USE AND SEEK MEDICAL ATTENTION. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) (FP N). =========================================================================== Transportation Data =========================================================================== =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 09APR98 Label Status: M Common Name: CASCADE LIQUIGEL, TP Chronic Hazard: NO Signal Word: DANGER! Acute Health Hazard-Slight: X Contact Hazard-Severe: X Fire Hazard-None: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE: INGEST: MAY CAUSE VOMITING & MODERATE TO SEVERE ORAL AND/OR GASTROINTESTINAL IRRITATION. SKIN/EYE CONT: MAY CAUSE MODERATE, TRANSIENT IRRITATION. SIGNS & SYMPS OF EXPOS: INGEST: POSSIBLE BURNING SENSATION & IRRITATION OF MOUTH AND THROAT & POSSIBLE NAUSEA, VOMITING AND/OR DIARRHEA. EYE CONT: MAY CAUSE STINGING, TEARING, ITCHING, SWELLING, AND/OR REDNESS. INHALATION: MAY CAUSE COUGHING, SORE THROAT, WHEEZING, OR TRANSITORY SHORTNESS OF BREATH. SKIN: CONTACT WITH NONE SPECIFIED BY MANUFACTURER. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: PROCTOR & GAMBLE Label Street: 11530 REED HARTMAN HIGHWAY Label City: CINCINNATI Label State: OH Label Zip Code: 45241-2422 Label Country: US Label Emergency Number: 800-526-8623