PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Permatex(R) All Purpose Spray Adhesive
82019
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Permatex(R) All Purpose Spray Adhesive
Item No.: 82019
Part No.: 118DA
Product Type: Aerosol sealant
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
n-HEXANE* 110-54-3 50-55
DIMETHYL ETHER 115-10-6 25-30
Non-hazardous ingredients Proprietary 20-25
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
n-HEXANE 50 ppm TWA 50 ppm TWA None
176mg/M3 180mg/M3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Irritation of eyes, skin and respiratory system.
May cause nervous system depression. Extreme
overexposure may result in unconsciousness and
possibly death.
Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and
nervous system damage.
Prolonged overexposure to hexane may cause damage
to nerve tissue of the arms and legs (peripheral
neuropathy ),resulting in muscular weakness and
loss of sensation. This effect may be increased by
the presence of methyl ethyl ketone.
Primary Routes of Entry: Exposure may be by inhalation and/or skin or eye
contact, depending on conditions of use. To
minimize exposure, follow recommendations for
proper use, ventilation, and personal protective
equipment.
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Permatex(R) All Purpose Spray Adhesive
Item No.: 82019
3. HAZARDS IDENTIFICATION (continued)
Signs and symptoms
of Exposure: Headache, dizziness, nausea, and loss of
coordination are indications of excessive exposure
to vapors or spray mists. Redness and itching or
burning sensation may indicate eye or excessive
skin exposure.
Existing Conditions
Aggravated by Exposure: None generally recognized.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
n-HEXANE DEV IRR NER REP NO NO NO
DIMETHYL ETHER CNS IRR NO NO NO
Non-hazardous ingredients No Data NO NO NO
-------------------------------------------------------------------------------
Abbreviations
CNS Central nervous system DEV Developmental
IRR Irritant NER Nervous System
REP Reproductive
4. FIRST AID MEASURES
Ingestion: Never give anything by mouth to an unconscious
person. Do not induce vomiting. Give several
glasses of water. Seek medical attention.
Inhalation: If affected, remove from exposure. Restore
breathing. Keep warm and quiet.
Skin Contact: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before
reuse.
Eye Contact: Flush eyes with large amounts of water for 15
minutes. Get medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: Less than 0°F (Propellant) Method: Tag closed cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon.
Unusual Fire or
Explosion Hazards: Isolate from heat, electrical equipment, sparks,
and open flame. Closed containers may explode when
exposed to extreme heat. Application to hot
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Permatex(R) All Purpose Spray Adhesive
Item No.: 82019
5. FIRE FIGHTING MEASURES (continued)
surfaces requires special precautions. During
emergency conditions overexposure to decomposition
products may cause a helath hazard. Symptoms may
not be immediately apparent. Obtain medical
attention.
Explosive Limits:
(% by volume in air)Lower 1.2%
(% by volume in air)Upper 27.0%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove all sources of ignition. Maintain good
ventilation. Soak up with an inert absorbent.
Store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Keep away from heat, sparks, and open flame.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Keep away from heat, sparks or open flame. Vapors
will accumulate readily and may ignite explosively
Keep away from eyes. Avoid breathing of vapor and
mists.Avoid skin contact. During use and until all
vapors are gone: Keep area ventilated. Do not
smoke. Extinguish all flames, pilot lights, and
heaters. Turn off stoves, electric tools and
appliances, and other sources of ignition. Consult
NFPA Code. Use approved bonding and grounding
procedures. Do not puncture, incinerate, or expose
to temperature above 120°F. Heat from sunlight
radiators, stoves, hot water, and other heat
sources could cause container to burst. Do not
take internally. Keep out ot the reach of children
Intentional misuse by deliberately concentrating
and inhaling the contents can be harmful or fatal.
Wash hands after using.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Wear safety spectacles with unperforated
sideshields.
Skin: Chemical resistant gloves.
Ventilation: Local exhaust preferable. General exhaust
acceptable if the exposure to materials in Section
2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107,
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Permatex(R) All Purpose Spray Adhesive
Item No.: 82019
8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued)
1910.108. If personal exposure cannot be
controlled below applicable limits by ventilation,
wear a properly fitted organic/particulate
respirator approved by NIOSH/MSHA for protection
against materials in Section 2.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Not available
Odor: Solvent
Boiling Point: Range: Less than 0°F to 156°F.
pH: Does not apply
Solubility in Water: Not available
Specific Gravity 0.72 (Base only)
Volatile Organic Compound
(EPA Method 24) 79.25%; 571 grams per liter of material
(Less federally exempt solvents)
Vapor Pressure: Not available
Vapor Density: More than 1 (base only)
Evaporation Rate
(Ether = 1) Faster
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Do not incinerate. Depressurize container.
Dispose of in accordance with federal, state and
and local regulations.
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Permatex(R) All Purpose Spray Adhesive
Item No.: 82019
13. DISPOSAL CONSIDERATIONS (continued)
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Aerosols, flammable n.o.s. (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Division 2.1 (More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1950 (More than 500 ml)
15. REGULATORY INFORMATION
CA Proposition 65: Warning: This product contains a chemical known to
the State of California to cause cancer.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 4
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2*
Flammability Hazard: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0002
.