PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Permatex(R) All Purpose Spray Adhesive 82019 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Permatex(R) All Purpose Spray Adhesive Item No.: 82019 Part No.: 118DA Product Type: Aerosol sealant 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % n-HEXANE* 110-54-3 50-55 DIMETHYL ETHER 115-10-6 25-30 Non-hazardous ingredients Proprietary 20-25 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) n-HEXANE 50 ppm TWA 50 ppm TWA None 176mg/M3 180mg/M3 Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Irritation of eyes, skin and respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Prolonged overexposure to hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy ),resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of methyl ethyl ketone. Primary Routes of Entry: Exposure may be by inhalation and/or skin or eye contact, depending on conditions of use. To minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Permatex(R) All Purpose Spray Adhesive Item No.: 82019 3. HAZARDS IDENTIFICATION (continued) Signs and symptoms of Exposure: Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. Existing Conditions Aggravated by Exposure: None generally recognized. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA n-HEXANE DEV IRR NER REP NO NO NO DIMETHYL ETHER CNS IRR NO NO NO Non-hazardous ingredients No Data NO NO NO ------------------------------------------------------------------------------- Abbreviations CNS Central nervous system DEV Developmental IRR Irritant NER Nervous System REP Reproductive 4. FIRST AID MEASURES Ingestion: Never give anything by mouth to an unconscious person. Do not induce vomiting. Give several glasses of water. Seek medical attention. Inhalation: If affected, remove from exposure. Restore breathing. Keep warm and quiet. Skin Contact: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Eye Contact: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 5. FIRE FIGHTING MEASURES Flash Point: Less than 0°F (Propellant) Method: Tag closed cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon. Unusual Fire or Explosion Hazards: Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Permatex(R) All Purpose Spray Adhesive Item No.: 82019 5. FIRE FIGHTING MEASURES (continued) surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a helath hazard. Symptoms may not be immediately apparent. Obtain medical attention. Explosive Limits: (% by volume in air)Lower 1.2% (% by volume in air)Upper 27.0% 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Remove all sources of ignition. Maintain good ventilation. Soak up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Keep away from heat, sparks, and open flame. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Keep away from heat, sparks or open flame. Vapors will accumulate readily and may ignite explosively Keep away from eyes. Avoid breathing of vapor and mists.Avoid skin contact. During use and until all vapors are gone: Keep area ventilated. Do not smoke. Extinguish all flames, pilot lights, and heaters. Turn off stoves, electric tools and appliances, and other sources of ignition. Consult NFPA Code. Use approved bonding and grounding procedures. Do not puncture, incinerate, or expose to temperature above 120°F. Heat from sunlight radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out ot the reach of children Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Wash hands after using. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Wear safety spectacles with unperforated sideshields. Skin: Chemical resistant gloves. Ventilation: Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Permatex(R) All Purpose Spray Adhesive Item No.: 82019 8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) 1910.108. If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Not available Odor: Solvent Boiling Point: Range: Less than 0°F to 156°F. pH: Does not apply Solubility in Water: Not available Specific Gravity 0.72 (Base only) Volatile Organic Compound (EPA Method 24) 79.25%; 571 grams per liter of material (Less federally exempt solvents) Vapor Pressure: Not available Vapor Density: More than 1 (base only) Evaporation Rate (Ether = 1) Faster 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Do not incinerate. Depressurize container. Dispose of in accordance with federal, state and and local regulations. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Permatex(R) All Purpose Spray Adhesive Item No.: 82019 13. DISPOSAL CONSIDERATIONS (continued) EPA Hazardous Waste Number D001 - Hazardous waste per 40CFR 261.21 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Consumer Commodity (Not more than 500 ml); Aerosols, flammable n.o.s. (More than 500 ml) Class or Division: Class 9 (Not more than 500 ml); Division 2.1 (More than 500 ml) UN or ID Number: ID 8000 (Not more than 500 ml); UN 1950 (More than 500 ml) 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2* Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0002 .